Up to three PtPPh3 fragments, originating from [Pt(PPh3)2(C2H4)], can be added to [Re2(CO)10] affording [Re2Ptn(mu-C0)2n(CO)10-2n(PPh3)n] (n = 1,2,3) mixed metal clusters, with structures based on electron short (46 valence electrons) Re2Pt triangles condensed on the Re-Re hinge.
Ciani, G., Moret, M., Sironi, A., Beringhelli, T., D'Alfonso, G., DELLA PERGOLA, R. (1990). Stepwise addition of PtPPh3 fragments on [Re2(CO)10]. X-Ray crystal structures of the complexes [Re2Pt n (µ-CO)2n (CO)10 - 2n (PPh3) n ](n= 2, 3), the first examples of tetra-and penta-nuclear rhenium-platinum mixed-metal clusters. JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS, 1990(23), 1668-1670 [10.1039/C39900001668].
Stepwise addition of PtPPh3 fragments on [Re2(CO)10]. X-Ray crystal structures of the complexes [Re2Pt n (µ-CO)2n (CO)10 - 2n (PPh3) n ](n= 2, 3), the first examples of tetra-and penta-nuclear rhenium-platinum mixed-metal clusters
MORET, MASSIMO;DELLA PERGOLA, ROBERTO
1990
Abstract
Up to three PtPPh3 fragments, originating from [Pt(PPh3)2(C2H4)], can be added to [Re2(CO)10] affording [Re2Ptn(mu-C0)2n(CO)10-2n(PPh3)n] (n = 1,2,3) mixed metal clusters, with structures based on electron short (46 valence electrons) Re2Pt triangles condensed on the Re-Re hinge.
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