Synthesis and Properties of Novel Surface Active Monomers Based on Derivatives of 4-Hydroxybutyric Acid and 6-Hydroxyhexanoic Acid

Novel surface active maleate and methacrylate monomers based on derivatives of ω-hydroxy carboxylic acids have been synthesized. The monomers comprise of hydrophobic alkyl chains and hydrophilic poly(ethylene glycol), quaternary ammonium, sulfonate and carboxylic fragments. Synthesized monomers sufficiently reduce surface tension at the aqueous solution-air interface. The copolymerization of synthesized monomers with 5-tert-butylperoxy-5-methyl-2-hexene-3-yne monomer and N-vinylpirrolidone in solvent and emulsion copolymerization of synthesized peroxide containing surface active monomer with styrene have been carried out. The synthesized surface active monomers have been shown to be suitable emulsifiers for obtaining polystyrene colloid dispersions. It has been ascertained that obtained surface active copolymers can form the stable interpolyelectrolyte complexes with oppositely charged polymers