Graphene‐Molecule Hybridization at a Ferromagnetic Interface

The introduction of a graphene (Gr) buffer layer between a ferromagnetic substrate and a metallorganic molecule is known to mediate the magnetic coupling between them, an effect attributed to a weak hybridization between graphene and molecule. In this paper, we present experimental evidence of this effect through a detailed investigation of the frontier electronic properties of iron phthalocyanine deposited on cobalt-supported graphene. Despite being physisorbed, the molecular adsorption on Gr/Co induces a sizeable charge transfer from graphene to the molecular macrocycle leading to the partial occupation of the LUMO and the appearance of an energetically localized hybrid state, which can be attributed to the overlap between the graphene pz state and the molecular macrocycle. Graphene is not inert either; the adsorption of the molecule induces doping and alters the Fermi velocity of both the hybrid minicone state and the Dirac cone. Similar effects are observed when the molecular periphery is decorated with fluorine atoms, known for their electron-withdrawing properties, with minimal changes in the energy alignment.Using angle-resolved photoemission and density functional theory, we show that introducing graphene as a buffer layer between a molecular layer and a ferromagnetic substrate nearly isolates the molecule electronically, yet hybridization persists. In particular, FePc/Gr/Co and F16FePc/Gr/Co reveal a pi hybrid state due to vertical interaction between graphene's pz state and the molecular pi core. image