The detailed analysis of the time resolved luminescence of a specifically designed fluorescent molecular rotor enables the direct monitoring of the self-assembly of a poly(N,N-dimethylacrylamide)-block-polystyrene (PDMA-b-PS) copolymer into core-corona nanoparticles. Comparison with bulk PS indicates hard confinement of the micelle core, due to the solvation of the hydrophilic PDMA corona
Vaccaro, G., Bianchi, A., Mauri, M., Bonetti, S., Meinardi, F., Sanguineti, A., et al. (2013). Direct monitoring of self-assembly of copolymeric micelles by a luminescent molecular rotor. CHEMICAL COMMUNICATIONS, 49(76), 8474-8476 [10.1039/c3cc44590a].
Direct monitoring of self-assembly of copolymeric micelles by a luminescent molecular rotor
VACCARO, GIANFRANCO;BIANCHI, ALBERTO;MAURI, MARTINO;BONETTI, SIMONE;MEINARDI, FRANCESCO;SANGUINETI, ALESSANDRO;SIMONUTTI, ROBERTO;BEVERINA, LUCA;MAURI, MICHELE
2013
Abstract
The detailed analysis of the time resolved luminescence of a specifically designed fluorescent molecular rotor enables the direct monitoring of the self-assembly of a poly(N,N-dimethylacrylamide)-block-polystyrene (PDMA-b-PS) copolymer into core-corona nanoparticles. Comparison with bulk PS indicates hard confinement of the micelle core, due to the solvation of the hydrophilic PDMA corona
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