A lucky break: A combination of steric pressure and electron asymmetry has provided the first example of a diiron dithiolate that is both rotated and basic. The present work establishes the feasibility of a hydride free rotated structure for the Hred state of the enzyme (see figure). Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Wang, W., Rauchfuss, T., Moore, C., Rheingold, A., DE GIOIA, L., Zampella, G. (2013). Crystallographic Characterization of a Fully Rotated, Basic Diiron Dithiolate: Model for the H-red State?. CHEMISTRY-A EUROPEAN JOURNAL, 19(46), 15476-15479 [10.1002/chem.201303351].

Crystallographic Characterization of a Fully Rotated, Basic Diiron Dithiolate: Model for the H-red State?

DE GIOIA, LUCA;ZAMPELLA, GIUSEPPE
2013

Abstract

A lucky break: A combination of steric pressure and electron asymmetry has provided the first example of a diiron dithiolate that is both rotated and basic. The present work establishes the feasibility of a hydride free rotated structure for the Hred state of the enzyme (see figure). Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Articolo in rivista - Articolo scientifico
De-Novo Design; Active-Site; Iron Hydrogenase; Fefe Hydrogenase; Mixed-Valent; Complexes; Activation; Exchange; Ligand
English
2013
19
46
15476
15479
none
Wang, W., Rauchfuss, T., Moore, C., Rheingold, A., DE GIOIA, L., Zampella, G. (2013). Crystallographic Characterization of a Fully Rotated, Basic Diiron Dithiolate: Model for the H-red State?. CHEMISTRY-A EUROPEAN JOURNAL, 19(46), 15476-15479 [10.1002/chem.201303351].
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/10281/48784
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