A lucky break: A combination of steric pressure and electron asymmetry has provided the first example of a diiron dithiolate that is both rotated and basic. The present work establishes the feasibility of a hydride free rotated structure for the Hred state of the enzyme (see figure). Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Wang, W., Rauchfuss, T., Moore, C., Rheingold, A., DE GIOIA, L., Zampella, G. (2013). Crystallographic Characterization of a Fully Rotated, Basic Diiron Dithiolate: Model for the H-red State?. CHEMISTRY-A EUROPEAN JOURNAL, 19(46), 15476-15479 [10.1002/chem.201303351].
Crystallographic Characterization of a Fully Rotated, Basic Diiron Dithiolate: Model for the H-red State?
DE GIOIA, LUCA;ZAMPELLA, GIUSEPPE
2013
Abstract
A lucky break: A combination of steric pressure and electron asymmetry has provided the first example of a diiron dithiolate that is both rotated and basic. The present work establishes the feasibility of a hydride free rotated structure for the Hred state of the enzyme (see figure). Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.File in questo prodotto:
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