Experimental and computational experiments show that the electrophile MeS+ attacks a single Fe center in Fe-2(propanedithiolate)(CO)(4)(PMe3)(2) followed by isomerization of this terminal thiolato complex to the corresponding mu-SMe derivative
Olsen, M., Gray, D., Rauchfuss, T., DE GIOIA, L., Zampella, G. (2011). Stereochemistry of electrophilic attack at 34e(-) dimetallic complexes: the case of diiron dithiolato carbonyls plus MeS+. CHEMICAL COMMUNICATIONS, 47(23), 6554-6556 [10.1039/c1cc10858a].
Stereochemistry of electrophilic attack at 34e(-) dimetallic complexes: the case of diiron dithiolato carbonyls plus MeS+
DE GIOIA, LUCA;ZAMPELLA, GIUSEPPE
2011
Abstract
Experimental and computational experiments show that the electrophile MeS+ attacks a single Fe center in Fe-2(propanedithiolate)(CO)(4)(PMe3)(2) followed by isomerization of this terminal thiolato complex to the corresponding mu-SMe derivative
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