Interpenetrated nanocomposites were formed by polymerization of acrylonitrile in a ultrahigh surface area (>5000 m2 g−1) porous framework. The resulting material realizes a hyperextended interface with uniform interdigitation of the two structures at the size limit of the individual molecular moieties. The confined poly(acrylonitrile) chains could be transformed into light-absorbing polyconjugated ladder polymers.
Comotti, A., Bracco, S., Mauri, M., Mottadelli, S., Ben, T., Qiu, S., et al. (2012). Confined Polymerization in Porous Organic Frameworks with an Ultrahigh Surface Area. ANGEWANDTE CHEMIE. INTERNATIONAL EDITION, 51(40), 10136-10140 [10.1002/anie.201205618].
Confined Polymerization in Porous Organic Frameworks with an Ultrahigh Surface Area
COMOTTI, ANGIOLINA
;BRACCO, SILVIA;MAURI, MARTINO;SOZZANI, PIERO ERNESTO
2012
Abstract
Interpenetrated nanocomposites were formed by polymerization of acrylonitrile in a ultrahigh surface area (>5000 m2 g−1) porous framework. The resulting material realizes a hyperextended interface with uniform interdigitation of the two structures at the size limit of the individual molecular moieties. The confined poly(acrylonitrile) chains could be transformed into light-absorbing polyconjugated ladder polymers.
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