Several catechols are obtained by reacting excess of the corresponding phenols with the tetrahydroborato copper(I) complex (4) and subsequent dioxygen oxidation of the intermediate copper(I) phenoxo complex (1).
Chioccara, F., DI GENNARO, P., Lamonica, G., Sebastiano, R., Rindone, B. (1991). Selective Ortho-Hydroxylation of phenols in copper(I) Complexes. TETRAHEDRON, 47(25), 4429-4434 [10.1016/S0040-4020(01)87111-8].
Selective Ortho-Hydroxylation of phenols in copper(I) Complexes
DI GENNARO, PATRIZIA;RINDONE, BRUNO
1991
Abstract
Several catechols are obtained by reacting excess of the corresponding phenols with the tetrahydroborato copper(I) complex (4) and subsequent dioxygen oxidation of the intermediate copper(I) phenoxo complex (1).
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