The anion [HFe3Rh(CO)12]2− was obtained by reaction of [HFe(CO)4]− with Rh2(CO)4Cl2 in refluxing THF. Its solid state structure consists of a tetrahedron of metal atoms with three edge-bridging and nine terminal carbonyl groups. The hydridic ligand bridges a face containing the rhodium atom.
DELLA PERGOLA, R., Garlaschelli, L., Demartin, F., Manassero, M., Masciocchi, N., Longoni, G. (1988). Synthesis and Crystal-Structure of [NET4]2[HFE3RH(CO)12], the 1st Tetranuclear Fe-Rh Hydridocarbonyl Cluster. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 352(3), C59-C62 [10.1016/0022-328X(88)83134-6].
Synthesis and Crystal-Structure of [NET4]2[HFE3RH(CO)12], the 1st Tetranuclear Fe-Rh Hydridocarbonyl Cluster
DELLA PERGOLA, ROBERTO;
1988
Abstract
The anion [HFe3Rh(CO)12]2− was obtained by reaction of [HFe(CO)4]− with Rh2(CO)4Cl2 in refluxing THF. Its solid state structure consists of a tetrahedron of metal atoms with three edge-bridging and nine terminal carbonyl groups. The hydridic ligand bridges a face containing the rhodium atom.
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