In the title compound two C‐atoms are located in the cavity of a cluster. The CċC distance in very short—only 1.49 Å (for comparison: CC single bond 1.54 Å)—but, as deduced from a consideration of the number of cluster valence electrons, a delocalized CC interaction is more probable than a localized one. (Figure Presented.) Copyright © 1984 by Verlag Chemie, GmbH, Germany
Arrigoni, A., Ceriotti, A., DELLA PERGOLA, R., Longoni, G., Manassero, M., Masciocchi, N., et al. (1984). Synthesis and Crystal Structure of the Dicarbido Bimetallic Cluster [CO6Ni2C2(Co)16]2−. ANGEWANDTE CHEMIE. INTERNATIONAL EDITION IN ENGLISH, 23(4), 322-323 [10.1002/anie.198403221].
Synthesis and Crystal Structure of the Dicarbido Bimetallic Cluster [CO6Ni2C2(Co)16]2−
DELLA PERGOLA, ROBERTO;
1984
Abstract
In the title compound two C‐atoms are located in the cavity of a cluster. The CċC distance in very short—only 1.49 Å (for comparison: CC single bond 1.54 Å)—but, as deduced from a consideration of the number of cluster valence electrons, a delocalized CC interaction is more probable than a localized one. (Figure Presented.) Copyright © 1984 by Verlag Chemie, GmbH, Germany
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