Enantioselective Darzens condensation has been achieved from optically active 2-methylbenzaldehyde(tricarbonyl)chromium;enantiomeric excesses are in the range 40-88%.
Baldoli, C., Delbuttero, P., Licandro, E., Maiorana, S., Papagni, A. (1987). ASYMMETRIC INDUCTION IN THE DARZENS REACTION BY USING AN ETA-6-CR(CO)3 COMPLEXED ARENE AS CHIRAL AUXILIARY. JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS(10), 762-764 [10.1039/c39870000762].
ASYMMETRIC INDUCTION IN THE DARZENS REACTION BY USING AN ETA-6-CR(CO)3 COMPLEXED ARENE AS CHIRAL AUXILIARY
PAPAGNI, ANTONIO
1987
Abstract
Enantioselective Darzens condensation has been achieved from optically active 2-methylbenzaldehyde(tricarbonyl)chromium;enantiomeric excesses are in the range 40-88%.
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