The phosphono analogues of GDP-N-acetyl-α-D-mannosamine (2) and TDP-α-L-rhamnose (4) have been synthesized by conversion of the phosphono analogues of N-acetyl-α-D-mannosamine 1-phosphate (1) and α-L-rhamnose 1-phosphate (3) into the corresponding tri-n-butylammonium salts and subsequent reaction with the proper NMP-morpholidate.
Cipolla, L., Klaps, E., LA FERLA, B., Nicotra, F. (1998). Synthesis of the isosteric phosphono analogues of GDP-N-Acetyl-alfa-D-Mannosamine and TDP-alfa-L-Rhamnose. CARBOHYDRATE LETTERS, 3, 173-178.
Synthesis of the isosteric phosphono analogues of GDP-N-Acetyl-alfa-D-Mannosamine and TDP-alfa-L-Rhamnose
CIPOLLA, LAURA FRANCESCA;LA FERLA, BARBARA;NICOTRA, FRANCESCO
1998
Abstract
The phosphono analogues of GDP-N-acetyl-α-D-mannosamine (2) and TDP-α-L-rhamnose (4) have been synthesized by conversion of the phosphono analogues of N-acetyl-α-D-mannosamine 1-phosphate (1) and α-L-rhamnose 1-phosphate (3) into the corresponding tri-n-butylammonium salts and subsequent reaction with the proper NMP-morpholidate.
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