The stepwise reaction of the ethylene-like molecule [Re2(μ-H) 2(CO)8] with [Pt(cod)2] (cod = cycloocta-1,5-diene) affords the triangular cluster [Re2Pt(μ-H) 2(CO)8(COd)] and then, under H2, the pentanuclear species [Re4Pt(μ-H)6(CO)16], with a bow-tie geometry of the metal cluster, which in basic media deprotonates reversibly to [Re4Pt(μ-H)5(CO)16] -.

Ciani, G., Moret, M., Sironi, A., Antognazza, P., Beringhelli, T., D'Alfonso, G., et al. (1991). Stepwise addition of [Re2(m-H)2(CO)8] to a labile Pt(0) complex. X-Ray crystal structures of the bow-tie clusters [Re4Pt(m-H)6-n)(CO)16]n- (n= 0,1). JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS, 1991(18), 1255-1257 [10.1039/C39910001255].

Stepwise addition of [Re2(m-H)2(CO)8] to a labile Pt(0) complex. X-Ray crystal structures of the bow-tie clusters [Re4Pt(m-H)6-n)(CO)16]n- (n= 0,1)

MORET, MASSIMO;DELLA PERGOLA, ROBERTO;
1991

Abstract

The stepwise reaction of the ethylene-like molecule [Re2(μ-H) 2(CO)8] with [Pt(cod)2] (cod = cycloocta-1,5-diene) affords the triangular cluster [Re2Pt(μ-H) 2(CO)8(COd)] and then, under H2, the pentanuclear species [Re4Pt(μ-H)6(CO)16], with a bow-tie geometry of the metal cluster, which in basic media deprotonates reversibly to [Re4Pt(μ-H)5(CO)16] -.
Articolo in rivista - Articolo scientifico
Rhenium; platinum; hydride ligands; heterometallic clusters;
English
1991
1991
18
1255
1257
none
Ciani, G., Moret, M., Sironi, A., Antognazza, P., Beringhelli, T., D'Alfonso, G., et al. (1991). Stepwise addition of [Re2(m-H)2(CO)8] to a labile Pt(0) complex. X-Ray crystal structures of the bow-tie clusters [Re4Pt(m-H)6-n)(CO)16]n- (n= 0,1). JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS, 1991(18), 1255-1257 [10.1039/C39910001255].
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/10281/10392
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